You can use the function – GetAdaptersInfo(). The network adapter information will be populated and filled back in IP_ADAPTER_INFO structure. In that structure, you can get the network adapter name, MAC address and a couple of other information. See the sample code snippet.

#include "Iphlpapi.h"
...
// Get the buffer length required for IP_ADAPTER_INFO.
ULONG BufferLength = 0;
BYTE* pBuffer = 0;
if( ERROR_BUFFER_OVERFLOW == GetAdaptersInfo( 0, &BufferLength ))
{
    // Now the BufferLength contain the required buffer length.
    // Allocate necessary buffer.
    pBuffer = new BYTE[ BufferLength ];
}
else
{
    // Error occurred. handle it accordingly.
}

// Get the Adapter Information.
PIP_ADAPTER_INFO pAdapterInfo =
      reinterpret_cast<PIP_ADAPTER_INFO>(pBuffer);
GetAdaptersInfo( pAdapterInfo, &BufferLength );

// Iterate the network adapters and print their MAC address.
while( pAdapterInfo )
{
    // Assuming pAdapterInfo->AddressLength is 6.
    CString csMacAddress;
    csMacAddress.Format(_T("%02x:%02x:%02x:%02x:%02x:%02x"),
                        pAdapterInfo->Address[0],
                        pAdapterInfo->Address[1],
                        pAdapterInfo->Address[2],
                        pAdapterInfo->Address[3],
                        pAdapterInfo->Address[4],
                        pAdapterInfo->Address[5]);

    cout << "Adapter Name :" << pAdapterInfo->AdapterName << " "
         << "MAC :" << (LPCTSTR) csMacAddress << endl;

    // Get next adapter info.
    pAdapterInfo = pAdapterInfo->Next;
}

// deallocate the buffer.
delete[] pBuffer;

Don’t forget to add Iphlpapi.lib to project settings.

Targeted Audience – Beginners.